Lionel Messi bagged himself a goal within 60 seconds of coming off the bench to heap the misery on Bolivia, who were already four behind.
Messi entered the fray in the 66th minute and had already headed home his 47th international goal before the clock hit 67 minutes.
The Barcelona star then added his 48th International goal 9 minutes later, rounding the keeper for a composed finish.
Man City star Sergio Aguero and PSG man Ezequiel Lavezzi also grabbed doubles, with Angel Correa of Atletico Madrid rounding off the scoring.
It was Argentina's first game since their Copa America final loss to Chile and they will kick off their World Cup qualifying campaign on the 8th of October in Buenos Aires, where the will face Ecuador.
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